Crystallographic and spectroscopic studies of a luminescent binuclear copper(I) complex containing mixed-ligands

摘要

the luminescent binuclear copper(I) complex[Cu(dppm)(phen)]_2(NO_3)_2 centre dot 6H_2O(dppm=Ph_2PCH_2PPh_2,phen=1,10-phenanthroline) has been prepared and characterized by phsicochemical and spectroscopic methods.The complex is photoluminescent at room temperature.Its X-ray crystal structure shows that dppm coordinates as a bridging ligand,and phen as a bidentate ligand to the copper (I) atoms of the tetrahedral structure.