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Electrochemical Investigation on the Corrosion of 18%Ni M250 Grade Maraging Steel under Welded Condition in Sulfuric Acid Medium

机译:焊接条件下18%Ni M250级马氏体时效钢在焊接条件下的腐蚀电化学研究

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摘要

The corrosion behavior of welded maraging steel in sulfuric acid solutions has been studied over a range of acid concentrations and solution temperatures by electrochemical techniques such as Tafel extrapolation and electrochemical impedance spectroscopy. The studies have revealed that the corrosion rate of welded maraging steel increases with the increase in temperature and increase in concentration of sulfuric acid in the medium. The thermodynamic parameters such as activation energy, enthalpy of activation and entropy of activation for the corrosion process are calculated. The results obtained through the two techniques are in good agreement. The surface morphology and surface composition of the corroded samples have been examined by scanning electron microscopy (SEM) and energy-dispersive X-ray (EDX) analysis, respectively.
机译:已通过Tafel外推法和电化学阻抗谱等电化学技术研究了马氏体时效钢在硫酸溶液中的腐蚀行为,该过程在一定范围的酸浓度和溶液温度下进行。研究表明,焊接马氏体时效钢的腐蚀速率随温度的升高和介质中硫酸浓度的升高而增加。计算了腐蚀过程的热力学参数,例如活化能,活化焓和活化熵。通过两种技术获得的结果非常吻合。腐蚀样品的表面形态和表面组成已分别通过扫描电子显微镜(SEM)和能量色散X射线(EDX)分析进行了检查。

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