首页> 外文期刊>Transactions of the Indian Institute of Metals >KINETICS AND MECHANISM OF IRON ORE -COAL COMPOSITE PELLETS REDUCTION
【24h】

KINETICS AND MECHANISM OF IRON ORE -COAL COMPOSITE PELLETS REDUCTION

机译:铁矿石-煤复合颗粒还原的动力学和机理

获取原文
获取原文并翻译 | 示例
       

摘要

Composite pellet contains mixture of fines of iron bearing oxide and carbonaceous material (coal, coke etc), which has been imparted sufficient green strength for subsequent handling by cold bonding technique. The composite pellets offer the advantage of reduction rate, utilization of fines and pollution control. During non-isothermal reduction of composite pellets, it is found that degree of reduction varies from 46 to 99 pet, depending upon pellets composition and heating rate. It is also observed that devolatilization of coal generates reducing gases (such as H_2, CO etc), A significant quantity (approximately 10 to 20 pet of pellet weight) of extraneous H_2O and CO_2 are retained by oven-dried pellets as chemically combined or strongly adsorbed species. These gases, liberate during heating to high temperature, react with carbon and hydrocarbon to generate additional quantities of CO and H_2. The paper analyses the non-isothermal kinetics data and discusses the mechanism of iron ore - coal composite pellets reduction. Activation energy values obtained for final stage reduction, vary from 183 to 268 KJ/ mol. Hence, it can be concluded that the overall rate of reduction of composite pellets is controlled by the rate of gasification reactions.
机译:复合粒料包含含铁氧化物和碳质材料(煤,焦炭等)的细粉混合物,已赋予其足够的生坯强度,以便通过冷粘合技术进行后续处理。复合颗粒的优点是降低率,利用细粉和控制污染。发现复合颗粒的非等温还原过程中,还原程度取决于颗粒的组成和加热速率,从46到99 pet不等。还观察到,煤的脱挥发分会产生还原性气体(例如H_2,CO等),大量(约10到20 pet的颗粒重量)外来H_2O和CO_2被化学方法或化学结合的烤箱干燥颗粒保留。吸附物质。这些气体在加热至高温时释放出来,与碳和碳氢化合物反应生成更多数量的CO和H_2。本文分析了非等温动力学数据,并探讨了铁矿石-煤复合颗粒还原的机理。最终还原所需的活化能值在183 KJ / mol至268 KJ / mol之间。因此,可以得出结论,复合颗粒的总还原速率由气化反应速率控制。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号