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首页> 外文期刊>Theoretical and Experimental Chemistry >Selective Reduction of No By C-3 and C-8 Alkanes Over Silver Catalysts on Structured Al2O3/Cordierite Supports
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Selective Reduction of No By C-3 and C-8 Alkanes Over Silver Catalysts on Structured Al2O3/Cordierite Supports

机译:结构化的Al2O3 /堇青石载体上银催化剂上C-3和C-8烷烃的No选择性还原

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摘要

An extremal dependence of the catalytic activity of Ag/Al2O3/cordierite on the silver content in the selective catalytic reduction of NO with propane and octane was discovered. The optimum content of Ag was higher during reduction with octane (0.5 wt.%) than with propane (0.3 wt.%). The role of the silver involves formation not only of oxidation-reduction centers but also of additional Lewis acid centers at which activation of the reagents (NO and C (n) H (m) ) occurs.
机译:发现在丙烷和辛烷选择性催化还原NO中,Ag / Al2O3 /堇青石的催化活性对银含量的极端依赖性。在用辛烷(0.5重量%)还原期间,Ag的最佳含量高于用丙烷(0.3重量%)还原时的最佳含量。银的作用不仅涉及氧化还原中心的形成,而且还涉及另外的路易斯酸中心的形成,在该处发生试剂的活化(NO和C(n)H(m))。

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