Rearrangement of 2,5-Bis(silylated)-N-Boc Pyrroles into the Corresponding 2,4-Species

Jean-Hugues Mirebeau; Mansour Haddad; Martin Henry-Ellinger; Gerard Jaouen; Julien Louvel; Franck Le Rideau

首页> 外文期刊>The Journal of Organic Chemistry >Rearrangement of 2,5-Bis(silylated)-N-Boc Pyrroles into the Corresponding 2,4-Species

【24h】

Rearrangement of 2,5-Bis(silylated)-N-Boc Pyrroles into the Corresponding 2,4-Species

机译：2,5-双（甲硅烷基化）-N-Boc吡咯的重排成相应的2,4-种类

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The rearrangement of 2,5-bis(silylated)-N-Boc pyrrolesin their 2,4-isomers is shown to proceed under mild acidicconditions. A reasonable mechanism, based on literatureas well as experiments, is proposed to rationalize thistransformation.

机译：2,5-双（甲硅烷基化）-N-Boc吡咯在其2,4-异构体中的重排显示在弱酸性条件下进行。提出了一种基于文献和实验的合理机制，以使这种转换合理化。

著录项

来源
《The Journal of Organic Chemistry》 |2009年第22期|共3页
作者
Jean-Hugues Mirebeau; Mansour Haddad; Martin Henry-Ellinger; Gerard Jaouen; Julien Louvel; Franck Le Rideau;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
rearrangement; mechanism; literature;

机译：重排;机制;文学;

相似文献

外文文献
中文文献
专利

1. Rearrangement of 2,5-Bis(silylated)-N-Boc Pyrroles into the Corresponding 2,4-Species [J] . Jean-Hugues Mirebeau, Mansour Haddad, Martin Henry-Ellinger, The Journal of Organic Chemistry . 2009,第22期

机译：2,5-双（甲硅烷基化）-N-Boc吡咯的重排成相应的2,4-种类
2. Rearrangement of 2,4-bisalkylpyrrole Unit to 2,5-bisalkylpyrrole Unit in the Ligand-Modified Porphyrinogens [J] . Chang-Hee Lee, Phil-Yeon Heo Bulletin of the Korean Chemical Society . 1996,第9期

机译：配体修饰的卟啉原中2,4-双烷基吡咯单元重排为2,5-双烷基吡咯单元
3. Rearrangement of 2,4-bisalkylpyrrole Unit to 2,5-bisalkylpyrrole Unit in the Ligand-Modified Porphyrinogens [J] . Chang-Hee Lee, Phil-Yeon Heo Bulletin of the Korean Chemical Society . 1996,第9期

机译：配体修饰的卟啉原中2,4-双烷基吡咯单元重排为2,5-双烷基吡咯单元
4. TTF derivative of 2,5-aromatic disubstituted pyrroles, experimental and theoretical study [C] . Lioudmila Fomina, Christopher Leon, Montserrat Bizarro, International Materials Research Congress . 2016

机译：TTF衍生物2,5-芳族二取代的胃果，实验和理论研究
5. STUDIES IN STEREOCHEMISTRY. PART I: SYNTHESIS, RESOLUTION AND ABSOLUTE CONFIGURATION OF (E)-2,4-DIMETHYL-2-HEXENOIC ACID. PART II: THE DETERMINATION OF THE HEAT OF HYDROGENATION AND REARRANGEMENT BEHAVIOR OF 1,1'-SPIROBIINDENE. PART III: SYNTHESIS AND CHIROPTICAL PROPERTIES OF 5,7-DIOXOBICYCLO(2.2.2)OCT-2-ENE AND BICYCLO(2.2.2)OCTAN-2,5-DIONE. [D] . MORTON, GERALD HUNT. 1980

机译：立体化学研究。第一部分：（E）-2,4-二甲基-2-己酸的合成，拆分和绝对构型。第二部分：1,1'-螺双茚的加氢热和重排行为的测定。第三部分：5,7-二氧杂双环（2.2.2）OCT-2-烯和双环（2.2.2）OCTAN-2,5-二酮的合成和手性。
6. 3,4-Bis(4-methoxyphenyl)-2,5-dihydro-1H-pyrrole-2,5-dione [O] . Liangzhu Huang, Youqiang Li, Dongmei Gao, 2015

机译：3,4-双（4-甲氧基氧基苯甲酰基）-2,5-二氢-1H-吡咯-2,5-二酮
7. Alkylidene-Centered Rearrangement of a Tantalum Alkylidene Alkoxide Species with the N,C,N-Bis-ortho-chelated 1,2,6-Trisubstituted Aryldiamine Ligand C6H3(CH2NMe2)2-2,6-to a Product with a C,N-Mono-ortho-chelated 1,2,4-Trisubstituted Aryldiamine Ligand. X-ray Molecular Structure of TaCl(CH-t-Bu){C6H3(CH2NMe2)2-2,4}(O-t-Bu)† [O] . Marco H. P. Rietveld, Elzebé G. Klumpers, Johann T. B. H. Jastrzebski, 1997

机译：用N，C，N-BIS-右螯合的1,2,6-三取代的阿里德二胺配体C6H3（CH2NME2）2-2,6 - 与C的产物为中心重新排列，N-单邻螯合的1,2,4-三取代的阿米基胺配体。 TaCl（CH-T-BU）{C6H3（CH2NME2）2-2-2,4}（O-T-BU）α的X射线分子结构。
8. Summary of an Oral Two-generation Reproduction Toxicity Study in Rats with 1 H-Pyrrole-2,5-dione, 1,1'-(1,3-phenylenebis (methylene))bis (3-methyl)-(Asterisks) 1. [R] . 2011

机译：用1 H-吡咯-2,5-二酮，1,1' - （1,3-亚苯基双（亚甲基））双（3-甲基） - （星号）1对大鼠进行口服两代繁殖毒性研究的总结。

Rearrangement of 2,5-Bis(silylated)-N-Boc Pyrroles into the Corresponding 2,4-Species

摘要

著录项

相似文献

相关主题

期刊订阅