Comment on 'Computer Simulation of Static and Dynamic Properties During Transient Sorption of Fluids in Mesoporous Materials'

摘要

Morgner presents a theory and calculations for adsorption/ desorption isotherms, self-diffusivity, and relaxation dynamics for fluid in a system of independent idealized cylindrical pores with diameters chosen from a distribution. His paper includes a critique of our work that indicates a serious misunderstanding of both the essential points in our articles and the physics of confined fluid behavior in the presence of quenched disorder. His theory for the equilibrium density distribution and free energy for a fluid in a cylindrical pore seems to be the local density approximation.