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Hydrodynamics of Domain Size Equilibration in Monolayers

机译:单层畴尺寸平衡的流体力学

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摘要

Coexisting thermodynamic phases of lipid molecules at the air-water interface often exhibit microscopically observable domains with a variety of sizes and shapes. The size and shape equilibration of these domains generally involve fluid flow in the monolayer as well as in the aqueous subphase. The present work treats the problem of the rate of size equilibration of a circular solid domain surrounded by a liquid composed of the same substance. The pressure at large distances from the domain is maintained constant, so that there is monolayer flow toward or away from the central domain. The central domain accordingly increases or decreases in size until a state of stable or metastable equilibrium is reached. Calculated rates of domain size change are discussed in terms of different experimental conditions, including applied electric fields.
机译:脂分子在空气-水界面处共存的热力学相通常表现出具有各种尺寸和形状的微观可观察区域。这些区域的大小和形状平衡通常涉及单层以及含水亚相中的流体流动。本工作解决了由相同物质组成的液体包围的圆形固体区域的尺寸平衡速率问题。与磁畴相距很远的压力保持恒定,因此有单层流体流向或离开中心磁畴。中心区域相应地增大或减小,直到达到稳定或亚稳态平衡状态。根据不同的实验条件(包括施加的电场)讨论了计算得出的畴尺寸变化率。

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