首页> 外文期刊>The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical >On the Relation between the Semiclassical Initial Value Representation and an Exact Quantum Expansion in Time-Dependent Coherent States
【24h】

On the Relation between the Semiclassical Initial Value Representation and an Exact Quantum Expansion in Time-Dependent Coherent States

机译:时变相干态中半经典初值表示与精确量子展开之间的关系

获取原文
获取原文并翻译 | 示例
           

摘要

The Hrman-Kluk (HK) or coherent state initial value representation (IVR) of semiclassical (SC) theory expresses a time-evolving wave function as a sum (integral) over the initial conditions of classically evolved coherent states (aka minimum uncertainty wave packets). An exact expansion of the wave function can also be made in terms of these same coherent states, thinking of them simply as a (time-dependent) basis set. This paper shows the precise set of approximations that are necessary to degenerate the exact expansion into the SC-IVR result. As a byproduct, we also obtain a generalization of the HK "prefactor".
机译:半经典(SC)理论的Hrman-Kluk(HK)或相干态初始值表示(IVR)在经典演化的相干态(也称为最小不确定性波包)的初始条件下,将时间演化波函数表示为一个和(积分) )。还可以根据这些相同的相干状态对波动函数进行精确扩展,将它们简单地视为(随时间变化的)基础集。本文展示了精确的近似值集,这些近似值对于将精确的扩展分解为SC-IVR结果是必需的。作为副产品,我们还获得了香港“前置因子”的概括。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号