It is demonstrated that single molecular arrays of phthalocyanines (Pc) can be assembled with templates of 2-dimensional alkane lamella of nanometer scale.By optimizing stoichiometry of the binary mixture,large arease of uniform single molecular arrays can be formed in submicrometer scale.This work provides a molecular scale illustration of self-assembly of binary molecular systems based on van der Waals interaction,and a method to design and assemble single molecular arrays with submicrometer length scale.
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