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The mechanism of thickness selection in the Sadler-Gilmer model of polymer crystallization

机译:聚合物结晶的Sadler-Gilmer模型中厚度选择的机理

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Recent work on the mechanism of polymer crystallization has led to a proposal for the mechanism of thickness selection which differs from those proposed by the surface nucleation theory of Lauritzen and Hoffman and the entropic barrier model of Sadler and Gilmer. This has motivated us to reexamine the model used by Sadler and Gilmer. We again find a fixed-point attractor which describes the dynamical convergence of the crystal thickness to a value just larger than the minimum stable thickness, l_(min). This convergence arises from the combined effect of two constraints on the length of stems in a layer: it is unfavorable for a stem to be shorter than l_(min) and for a stem to overhang the edge of the previous layer. The relationship between this new mechanism and the explanation given by Sadler and Gilmer in terms of an entropic barrier is discussed. We also examine the behavior of the Sadler-Gilmer model when an energetic contribution from chain folds is included.
机译:聚合物结晶机理的最新研究为厚度选择的机理提出了一个建议,该机理不同于Lauritzen和Hoffman的表面成核理论以及Sadler和Gilmer的熵垒模型所提出的。这促使我们重新审视萨德勒和吉尔默使用的模型。我们再次找到一个定点吸引子,该吸引子将晶体厚度的动态收敛描述为刚好大于最小稳定厚度l_(min)的值。这种收敛是由于两个约束对一层中茎长度的综合影响而产生的:不利的是,茎短于l_(min)且茎伸出上一层的边缘。讨论了这种新机制与萨德勒和吉尔默关于熵屏障的解释之间的关系。当包括来自链折叠的能量贡献时,我们还检查了萨德勒-吉尔默模型的行为。

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