Substituted and Spiro-annelated Perhydro-1,2,3-oxathiazine 2,2-Dioxides and 1-Benzyl-4-methylazetidines

A. V. Varlamov; N. V. Sidorenko; F. I. Zubkov; A. I. Chernyshev; K. F. Turchin

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Substituted and Spiro-annelated Perhydro-1,2,3-oxathiazine 2,2-Dioxides and 1-Benzyl-4-methylazetidines

机译：取代和螺旋退火的过氢1,2-，3-恶二嗪2,2-二氧化物和1-苄基-4-甲基氮杂环丁烷

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We obtained perhydro-1,2,3-oxathiazine 2,2-dioxides by cyclization of 4-N-benzylamino-4-tetramethylene(phenyl-, methylphenyl-, dimethyl)but-1-enes in conc. H2SO4 at 25°C. When treated with an alcoholic solution of base, the oxathiazines are converted to 2-substituted and spiro-annelated 1-benzyl-4-methylazetidines.

机译：我们通过浓缩4-N-苄基氨基-4-四亚甲基（苯基-，甲基苯基-，二甲基）丁-1-烯的环化反应获得过氢-1,2,3-氧杂噻嗪2,2-二氧化物。 25°C的H2SO4。当用碱的醇溶液处理时，草ath嗪被转化为2-取代的和螺线退火的1-苄基-4-甲基氮杂环丁烷。

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来源
《Chemistry of heterocyclic compounds》 |2004年第8期|共9页
作者
A. V. Varlamov; N. V. Sidorenko; F. I. Zubkov; A. I. Chernyshev; K. F. Turchin;
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正文语种 eng
中图分类杂环化合物;
关键词
azetidines; homoallyl amines; 1; 2; 3-oxathiazine 2; 2-dioxides;

机译：氮杂环丁烷;高烯丙基胺;1;2;3-氧杂噻嗪2;2-二氧化物;

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1. Substituted and Spiro-annelated Perhydro-1,2,3-oxathiazine 2,2-Dioxides and 1-Benzyl-4-methylazetidines [J] . A. V. Varlamov, N. V. Sidorenko, F. I. Zubkov, Chemistry of heterocyclic compounds . 2004,第8期

机译：取代和螺旋退火的过氢1,2-，3-恶二嗪2,2-二氧化物和1-苄基-4-甲基氮杂环丁烷
2. Pd-catalyzed [3+2] cycloaddition of vinylcyclopropanes with 1-azadienes: synthesis of 4-cyclopentylbenzo[e][1,2,3]oxathiazine 2,2-dioxides [J] . Lin Yan, Wang Qijun, Wu Yang, RSC Advances . 2018,第71期

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3. Asymmetric Mannich Reaction of Aryl Methyl Ketones with Cyclic Imines Benzo[e][1,2,3]oxathiazine 2,2-Dioxides Catalyzed by Cinchona Alkaloid-based Primary Amines [J] . Cui Xiao-Yu, Duan Hui-Xin, Zhang Yongna, Chemistry, an Asian journal . 2016,第21期

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Substituted and Spiro-annelated Perhydro-1,2,3-oxathiazine 2,2-Dioxides and 1-Benzyl-4-methylazetidines

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