SYNTHESIS OF CYCLOPROPYL-SUBSTITUTED 4H-3,1-BENZOXAZINES FROM 2-AMINO-PHENYL CYCLOPROPYL KETONES AND 2-CYCLOPROPANOYLAMINOACYLBENZENES

Mochalov SS; Khasanov MI; Zefirov NS

首页> 外文期刊>Chemistry of heterocyclic compounds >SYNTHESIS OF CYCLOPROPYL-SUBSTITUTED 4H-3,1-BENZOXAZINES FROM 2-AMINO-PHENYL CYCLOPROPYL KETONES AND 2-CYCLOPROPANOYLAMINOACYLBENZENES

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SYNTHESIS OF CYCLOPROPYL-SUBSTITUTED 4H-3,1-BENZOXAZINES FROM 2-AMINO-PHENYL CYCLOPROPYL KETONES AND 2-CYCLOPROPANOYLAMINOACYLBENZENES

机译：由2-氨基-苯基环丙基酮和2-环丙酰基氨基酰苯合成环丙基取代的4H-3,1-苯并恶嗪

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摘要

2- and 4-cyclopropyl- and 2,4-dicyclopropyl-substituted 4H-3,1-benzoxazines were synthesized by the intramolecular acid catalyzed heterocyclization of ortho-acylamino-substituted benzyl alcohols, obtained from 2-aminophenyl cyclopropyl ketones and 2-cyclopropanoylaminoacylbenzenes.

机译：通过由2-氨基苯基环丙基酮和2-环丙酰基氨基酰基苯制得的邻酰基氨基取代的苄醇的分子内催化杂环合成2-和4-环丙基-和2,4-二环丙基-取代的4H-3,1-苯并恶嗪。

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来源
《Chemistry of heterocyclic compounds》 |2009年第2期|共14页
作者
Mochalov SS; Khasanov MI; Zefirov NS;
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正文语种 eng
中图分类杂环化合物;
关键词
7-acyl-6-amino-1; 4-benzodioxane; 4-amino-5-cyclopropanoylveratrole; 7-acyl-6-acylamino-1; 4-benzodioxanes; 2-acylamino-4; 5-dimethoxybenzyl alcohols; 4-acylamino-5-cyclopropanoylveratroles; 2-acylamino-4; 5-ethylenedioxybenzyl alcohols; 6-cyclopropanoyl-1; 4-benzodioxane; 4-cyclopropanoylveratrole; cyclopropyl-substituted 4H-3; 1-benzoxazines; intramolecular heterocyclization;

机译：7-酰基-6-氨基-1;4-苯并二恶烷;4-氨基-5-环丙酰基-1;4-酰基-6-酰基氨基-1;4-苯并二恶烷;2-酰基氨基-4;5-二甲氧基苄醇;4-酰基氨基-5-环丙酰基维甲酸;2-酰基氨基-4;5-乙二氧基苄醇;6-环丙酰基-1;4-苯并二恶烷;4-环丙酰基维甲酸;环丙基取代的4H-3;1-苯并恶嗪;分子内杂环化;

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1. SYNTHESIS OF CYCLOPROPYL-SUBSTITUTED 4H-3,1-BENZOXAZINES FROM 2-AMINO-PHENYL CYCLOPROPYL KETONES AND 2-CYCLOPROPANOYLAMINOACYLBENZENES [J] . Mochalov SS, Khasanov MI, Zefirov NS Chemistry of heterocyclic compounds . 2009,第2期

机译：由2-氨基-苯基环丙基酮和2-环丙酰基氨基酰苯合成环丙基取代的4H-3,1-苯并恶嗪
2. Efficient Synthesis of 4H-3,1-Benzoxazine Derivatives via One-Pot Sequential Passerini-Azide/Palladium-Catalyzed Azide-Isocyanide Coupling/Cyclization Reaction [J] . Feng Qi-Xun, Mu Zhi-Ying, Yao Gang, Synlett . 2020,第10期

机译：通过单盆顺序链静脉/钯催化叠氮化物 - 异氰化物偶联/环化反应的高效合成4H-3,1-苯并恶嗪衍生物
3. A Facile Synthesis of 4-Tetrazolyl-Substituted 4H-3,1-Benzoxazines through Sequential Passerini-Azide/Acylation/Catalytic Aza-Wittig Reaction [J] . Ren Zhi-Lin, Liu Jian-Chao, Ding Ming-Wu Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2017,第4期

机译：通过顺序路静叠氮化物/酰化/催化AZA-Witger反应，容易合成4-四唑基取代的4H-3,1-苯并恶嗪
4. Formation and reactivity of six-membered hetero-nickelacycles by oxidative addition of cyclopropyl ketones and cyclopropyl imines [C] . Takashi Tamaki, Midue Nagata, Masato Ohashi Symposium on Organometallic Chemistry . 2008

机译：通过氧化添加环丙基酮和环丙基亚胺的六元杂镍的形成和反应性
5. I. Progress towards the synthesis of plakortether B through a zinc-mediated homologation. II. Synthesis of novel hydroxy-cyclopropyl peptides isosteres. [D] . Taschner, Ian Scott. 2011

机译：I.通过锌介导的同系物合成普拉克他醚B的进展。二。新型羟基-环丙基肽等排体的合成。
6. Synthesis of (Het)aryl 2-(2-hydroxyaryl)cyclopropyl Ketones [O] . Alexander A. Fadeev, Alexey O. Chagarovskiy, Anton S. Makarov, 2020

机译：（HET）芳基2-（2-羟基芳基）环丙基酮的合成
7. Synthesis of cyclopropyl-substituted furans by Brønsted acid promoted cascade reactions [O] . Clark, J. Stephen, Romiti, Filippo, Hogg, Kirsten F., 2015

机译：布朗斯台德酸促进级联反应合成环丙基取代的呋喃
8. SYNTHESIS OF CYCLOPROPANE HYDROCARBONS FROM METHYLCYCLOPROPYL KETONE III - Z-CYCLOPROPYL-1-BUTENE, cis AND trans 2-CYCLOPROPYL-2-BUTENE, AND 2-CYCLOPROPYLBUTANE [R] . Vernon A. Slabey, Paul H. Wise 1951

机译：由甲基丙基丙酮酮III-Z-环丙基-1-丁烯，顺式和反式2-环丙基-2-丁烯和2-环丙基丁烷合成环丙烷烃

SYNTHESIS OF CYCLOPROPYL-SUBSTITUTED 4H-3,1-BENZOXAZINES FROM 2-AMINO-PHENYL CYCLOPROPYL KETONES AND 2-CYCLOPROPANOYLAMINOACYLBENZENES

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