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Surface roughness induced cracks of the deposition film from drying colloidal suspension

机译:干燥胶体悬浮液会导致表面粗糙度导致沉积膜产生裂纹

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摘要

We investigate crack formation in deposition films from drying colloidal suspension drops, by varying the roughness and texture of the substrate. The experimental results indicate that the crack number or crack spacing presents a general dependence on the substrate roughness, despite the orientation of the substrate textures. Interestingly, the crack spacing decreases with the increase of the roughness. Two possible mechanisms are proposed to understand the dependence of the cracks on roughness. Firstly, the concentration reduction of the drying suspension due to collecting colloidal particles from the substrate textures decreases the crack spacing. Secondly, stress concentration resulting from the defects (the notches in textures) in the dried deposition enhances crack formation. However, a quantitative estimation by the calculation of the stress concentrating factors reveals that the notch of the substrate textures dominates crack variation. The results here bring forth a practical method for controlling the crack orientation and suppression, and a potential application to crack-free coatings, films and paintings during the drying of complex fluids.
机译:我们通过改变基质的粗糙度和质地,研究了干燥胶体悬浮液液滴在沉积膜中形成的裂纹。实验结果表明,尽管基底纹理的取向不同,但裂纹数量或裂纹间距总体上取决于基底粗糙度。有趣的是,裂纹间距随着粗糙度的增加而减小。提出了两种可能的机制来理解裂纹对粗糙度的依赖性。首先,由于从基底纹理中收集胶体颗粒而导致的干燥悬浮液的浓度降低,从而减小了裂纹间距。其次,由干燥沉积中的缺陷(纹理的缺口)引起的应力集中会增强裂纹的形成。但是,通过应力集中系数的计算进行的定量估计表明,基板纹理的缺口占主导地位的裂纹变化。此处的结果提出了一种控制裂纹取向和抑制的实用方法,并潜在地应用于复杂流体干燥过程中的无裂纹涂层,薄膜和油漆。

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