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Confined flows of a polymer microgel

机译:聚合物微凝胶的密闭流动

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In this paper, we probe the influence of confinement on the flows of a polymer microgel, namely Carbopol. We compare its bulk rheological behavior, measured with a rheometer and well described by a Hershel-Bulkley law, to velocity profiles measured in rough microchannels, obtained with a particle tracking velocimetry technique. We show a strong disagreement between the bulk prediction for the velocity profiles and the measured ones in the microchannels. Velocity profiles in confined conditions are successfully analyzed within the framework of a non-local fluidity model introduced recently (J. Goyon et al. Nature, 454, 84 (2008)). This allows to determine a cooperativity length ξ, whose order of magnitude compares with the structure size of the microgel. Moreover, we measure flow curves using a rheometer for different gap conditions and also show that this set of data exhibit a strong effect of the confinement on the measured rheological properties. This is again characterized by a typical length of the same order as the cooperativity length scale ξ. We thus evidence confinement effects with two complementary experiments which both give the same typical length for the rearrangements in the flows.
机译:在本文中,我们探讨了限制对聚合物微凝胶(即Carbopol)流动的影响。我们将使用流变仪测量并由Hershel-Bulkley法则很好描述的其整体流变行为与通过粒子跟踪测速技术获得的在粗糙微通道中测得的速度分布进行比较。我们在速度曲线的整体预测与微通道中的测得的速度之间显示出强烈的分歧。在最近引入的非局部流动性模型的框架内,已成功地分析了受限条件下的速度分布(J. Goyon等,Nature,454,84(2008))。这允许确定协同作用长度ξ,其数量级与微凝胶的结构尺寸相比。此外,我们使用流变仪测量了不同间隙条件下的流动曲线,并且还表明,这组数据对所测流变性质表现出局限性。这又以与合作性长度标度ξ相同数量级的典型长度为特征。因此,我们用两个互补实验证明了约束作用,两个实验都为流中的重排提供了相同的典型长度。

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