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首页> 外文期刊>The European physical journal, E. Soft matter >Effect of salt on the compression of polyelectrolyte brushes in a theta solvent
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Effect of salt on the compression of polyelectrolyte brushes in a theta solvent

机译:盐对theta溶剂中聚电解质电刷压缩的影响

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Classical strong-stretching theory (SST) predicts that, as opposing polyelectrolyte brushes are compressed together in a salt-free theta solvent, they contract so as to maintain a finite polymer-free gap, which offers a potential explanation for the ultra-low frictional forces observed in experiments despite the application of large normal forces. However, the SST ignores chain fluctuations, which would tend to close the gap resulting in physical contact and in turn significant friction. In a preceding study, we examined the effect of fluctuations using self-consistent field theory (SCFT) and illustrated that high normal forces can still be applied before the gap is destroyed. We now look at the effect of adding salt. It is found to reduce the long-range interaction between the brushes but has little effect on the short-range part, provided the concentration does not enter the salted-brush regime. Consequently, the maximum normal force between two planar brushes at the point of contact is remarkably unaffected by salt. For the crossedcylinder geometry commonly used in experiments, however, there is a gradual reduction because in this case the long-range part of the interaction contributes to the maximum normal force.
机译:经典的强拉伸理论(SST)预测,当相对的聚电解质电刷在无盐的theta溶剂中压缩在一起时,它们会收缩以保持有限的无聚合物间隙,这为超低摩擦力提供了可能的解释。尽管施加了较大的法向力,但在实验中观察到的力。但是,SST忽略了链条波动,链条波动会趋于缩小间隙,从而导致物理接触并进而产生显着的摩擦。在先前的研究中,我们使用自洽场理论(SCFT)检查了波动的影响,并说明了在破坏间隙之前仍可以施加较高的法向力。现在我们来看添加盐的效果。已发现可以减少刷子之间的远程相互作用,但对短程部分影响很小,只要浓度不进入盐化刷子状态即可。因此,两个平面刷在接触点之间的最大法向力不受盐的影响。但是,对于实验中常用的交叉圆柱几何形状,会逐渐减小,因为在这种情况下,相互作用的远程部分会导致最大法向力。

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