First intermolecular Pauson-Khand reaction of 7-azanorbornenes. Control of the regioselectivity by the effect of the substituents attached to the olefinic partner

Odon Arjona; Aurelio G.Csaky; Rocio Medel; Joaquin Plumet

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First intermolecular Pauson-Khand reaction of 7-azanorbornenes. Control of the regioselectivity by the effect of the substituents attached to the olefinic partner

机译：7-氮杂降冰片的第一个分子间Pauson-Khand反应。通过连接到烯烃配偶体上的取代基的作用控制区域选择性

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High regioselectivity in the intermolecular Pauson-Khand reaciton of 7-azanorborn-5-enes has been found by using 5-bromo-2-endo-tosyl derivatives as the olefinic partner

机译：通过使用5-溴-2-内-甲苯基衍生物作为烯烃配体发现了7-氮杂orborn-5-烯的分子间Pauson-Khand反应中的高区域选择性

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2001年第17期|共3页
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Odon Arjona; Aurelio G.Csaky; Rocio Medel; Joaquin Plumet;
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中图分类有机化学;
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1. First intermolecular Pauson-Khand reaction of 7-azanorbornenes. Control of the regioselectivity by the effect of the substituents attached to the olefinic partner [J] . Odon Arjona, Aurelio G.Csaky, Rocio Medel, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2001,第17期

机译：7-氮杂降冰片的第一个分子间Pauson-Khand反应。通过连接到烯烃配偶体上的取代基的作用控制区域选择性
2. Regioselective Pauson-Khand processes with allylphosphonates as the olefinic partners [J] . Brown JA, Janecki T, Kerr WJ Synlett . 2005,第13期

机译：烯丙基膦酸酯为烯烃配偶体的区域选择性Pauson-Khand方法
3. Regioselectivity in intermolecular pauson-khand reactions of dissymmetric fluorinated alkynes [J] . Kizirian J.-C., Aiguabella N., Pesquer A., Organic letters . 2010,第24期

机译：不对称氟化炔烃分子间pauson-khand反应中的区域选择性
4. Pauson-Khand reactions of alkynyl-2-py rones: origin of regioselectivity and facile electrocyclization reactions(Abstracts) [C] . Benjamin E. Moulton, Ciara T. OBrien, Robert A. Jennings European Symposium on Organic Chemistry . 2007

机译：丙酮-2-PY rones的Pauson-k手反应：地区的起源和容易电宽反应（摘要）
5. CONTROL OF REGIOSELECTIVITY AND EXCITED SINGLET REACTION RATES BY SUBSTITUTION IN THE DI-PI-METHANE REARRANGEMENT. MECHANISTIC AND EXPLORATORY PHOTOCHEMISTRY [D] . WELTER, THOMAS ROBERT. 1977

机译：通过取代DI-PI-甲醇重排来控制区域选择性和激发的单价反应速率。力学和探索性光化学
6. Regioselective phenylene-fusion reactions of Ni(ii)-porphyrins controlled by an electron-withdrawing meso-substituent [O] . Norihito Fukui, Seung-Kyu Lee, Kenichi Kato, 2016

机译：Ni（ii）-卟啉的区域选择性亚苯基-稠合反应受吸电子介观取代基的控制
7. Regioselective phenylene-fusion reactions of Ni(II)-porphyrins controlled by an electron-withdrawing: Meso -substituent [O] . Fukui, Norihito, Lee, Seung Kyu, Kato, Kenichi, 2016

机译：吸电子控制的Ni（II）-卟啉的区域选择性亚苯基-稠合反应：中位取代基
8. Reaction of gem-Dichloroallyllithium with Aldehydes, Ketones, and Other Organic Substrates. An Example of Electronic Control of Regioselectivity in the Reactions of an Ambident Nucleophile. [R] . Seyferth, D., Murphy, G. J., Mauze, B. 1977

机译：宝石 - 二氯烯丙基锂与醛，酮和其他有机基质的反应。环境亲核试剂反应中区域选择性的电子控制实例。

First intermolecular Pauson-Khand reaction of 7-azanorbornenes. Control of the regioselectivity by the effect of the substituents attached to the olefinic partner

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