REACTION OF 3-AROYLAZIRIDINES WITH DIPHENYLCYCLOPROPENONE AND SUBSEQUENT STEREOSPECIFIC 1,3-DIPOLAR CYCLOADDITION OF THE ADDUCTS WITH DIMETHYL 1-CYCLOBUTENE 1,2-DICARBOXYLATE

Matsumoto K.; Kakehi A.; Shigihara A.; Lown JW.; Ikemi Y.

首页> 外文期刊>Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry >REACTION OF 3-AROYLAZIRIDINES WITH DIPHENYLCYCLOPROPENONE AND SUBSEQUENT STEREOSPECIFIC 1,3-DIPOLAR CYCLOADDITION OF THE ADDUCTS WITH DIMETHYL 1-CYCLOBUTENE 1,2-DICARBOXYLATE

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REACTION OF 3-AROYLAZIRIDINES WITH DIPHENYLCYCLOPROPENONE AND SUBSEQUENT STEREOSPECIFIC 1,3-DIPOLAR CYCLOADDITION OF THE ADDUCTS WITH DIMETHYL 1-CYCLOBUTENE 1,2-DICARBOXYLATE

机译：3-芳基氮丙啶与二苯并环戊烯酮的反应以及随后的立体特定的1,3-二烯丙基环戊二烯1,2-二羧酸二丁酯的加成反应

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Reaction of 3-aroylaziridines with diphenylcyclopropenone provides anhydro-3-hydroxy-2,4-diphenyl-6-arylpyrlium hydroxides that undergo stereospecific 1,3-dipolar cycloaddition with dimethyl l-cyclobutene 1,2-dicarboxylate to give the corresponding exo- and endo-adducts depending on the substituents of the 6-phenyl group. [References: 40]

机译：3-芳基氮丙啶与二苯基环丙烯酮的反应提供了脱水-3-羟基-2,4-二苯基-6-芳基py氢氧化物，该立体氢氧化物经历了立体有规的1,3-偶极环加成反应，并与1-环丁烯二甲酯1,2-二羧酸二甲酯形成相应的外-和-内加成物取决于6-苯基的取代基。 [参考：40]

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来源
《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |1995年第30期|共4页
作者
Matsumoto K.; Kakehi A.; Shigihara A.; Lown JW.; Ikemi Y.;
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正文语种 eng
中图分类有机化学;
关键词
Diels-alder reaction; Semiempirical methods; Transition structures; Carbonyl ylides; 4; 5-dihydro-1h-azepines; Cyclopentadiene; Cyclobutenes; Optimization; Parameters; Butadiene;

机译：Diels-alder反应;半经验方法;过渡结构;碳酰内酯;4;5-二氢-1h-氮杂;环戊二烯;环丁烯;优化;参数;丁二烯;

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1. REACTION OF 3-AROYLAZIRIDINES WITH DIPHENYLCYCLOPROPENONE AND SUBSEQUENT STEREOSPECIFIC 1,3-DIPOLAR CYCLOADDITION OF THE ADDUCTS WITH DIMETHYL 1-CYCLOBUTENE 1,2-DICARBOXYLATE [J] . Matsumoto K., Kakehi A., Shigihara A., Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1995,第30期

机译：3-芳基氮丙啶与二苯并环戊烯酮的反应以及随后的立体特定的1,3-二烯丙基环戊二烯1,2-二羧酸二丁酯的加成反应
2. Synthesis of 3,5-diaryl-4-chlorophthalates by (4+2) cycloaddition of 1-ethoxy-2-chloro-1,3-bis(trimethylsilyloxy)-1,3-diene with dimethyl acetylene dicarboxylate and subsequent site-selective Suzuki-Miyaura reactions [J] . Obaid-Ur-Rahman Abid, Muhammad Farooq Ibad, Muhammad Nawaz Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2010,第4期

机译：通过1-乙氧基-2-氯-1,3-双（三甲基甲硅烷基氧基）-1,3-二烯与乙炔二羧酸二甲酯的（4 + 2）环加成反应合成3,5-二芳基-4-氯邻苯二甲酸酯铃木宫浦的反应
3. Effect of solvent nature on the regioselectivity of the reactions of pyridinium ylides with E-1,2-di(alkylsulfonyl)-1,2-dichloroethene. from the reaction of 1,3-dipolar cycloaddition to the reaction of nucleophilic addition-elimination (Ad_N-E_(1,5)) [J] . Dontsova N.E., Nesterov V.N., Shestopalov A.M. Tetrahedron . 2013,第24期

机译：溶剂性质对吡啶鎓叶立德与E-1,2-二（烷基磺酰基）-1,2-二氯乙烯反应的区域选择性的影响。从1,3-偶极环加成反应到亲核加成消除反应（Ad_N-E_（1,5））
4. CONSTRUCTION OF NOVEL SUGAR DERIVATIVES VIA SUCCESSIVE MICHAEL ADDITION - 1,3-DIPOLAR CYCLOADDITION REACTIONS [C] . Luginina J., Rjabovs V., Turks M. International Carbohydrate Symposium . 2013

机译：通过连续迈克尔加法构建新型糖衍生物 - 1,3-偶极环加成反应
5. The development of a 1,3-dipolar cycloaddition reaction with 1,5-dimethyl-3-phenyl-6-oxoverdazyl radical [D] . Takahito, Kasahara 2007

机译：与1,5-二甲基-3-苯基-6-氧过二氮杂基的1,3-偶极环加成反应的发展
6. Ethyl 7′-(6-benzyloxy-2,2-dimethyltetrahydrofuro[3,2-d][1,3]dioxol-5-yl)-2-oxo-5′,6′,7′,7a’-tetrahydro-1′H,2H-spiro[acenaphthylene-1,5′-pyrrolo[1,2-c][1,3]thiazole]-6′-carboxylate [O] . G. Jagadeesan, K. Sethusankar, R. Prasanna, 2015

机译：乙基7'-（6-苄氧基-2,2-二甲基四氢呋喃[3,2-d] [1,3]二恶酚-5-基）-2-oxo-5'，6'，7'，7a'-四氢乙基-1'H，2H-螺[[-1,5'-吡咯并[1,2-c] [1,3]噻唑] -6'-羧酸盐
7. 1,3-Dipolar cycloaddition reactions of monocyclic aziridines with dimethyl 1-cyclobutene-1,2-dicarboxylate [O] . Kiyoshi Matsumoto, Hirokazu Iida, Takane Uchida, 1994

机译：1,3-偶极环加成反应单环氮化萘二甲基二甲基 - 环丁烯-1,2-二羧酸盐

REACTION OF 3-AROYLAZIRIDINES WITH DIPHENYLCYCLOPROPENONE AND SUBSEQUENT STEREOSPECIFIC 1,3-DIPOLAR CYCLOADDITION OF THE ADDUCTS WITH DIMETHYL 1-CYCLOBUTENE 1,2-DICARBOXYLATE

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