Nucleophilic displacement of homoallylic tosylates: influence of steric hindrance and conformational rigidity

A.Fernandez-Mateos; M.Rentzsch; L.Rodriguez Sanchez; R.Rubio Gonzalez

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Nucleophilic displacement of homoallylic tosylates: influence of steric hindrance and conformational rigidity

机译：均烯丙基甲苯磺酸盐的亲核取代：位阻和构象刚度的影响

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摘要

A comparative study on the nucleophilic displacement of homoallylic tosylates with different degrees of hindrance and rigidity is reported. #pi# Bond participation is favoured by hindrance and rigidity, and also by weak nucleophiles such as water or dimethylformamide.

机译：报道了具有不同程度的阻碍和刚性的均烯丙基甲苯磺酸盐的亲核取代作用的比较研究。阻碍和刚性以及弱亲核试剂（例如水或二甲基甲酰胺）有利于键的参与。

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《Tetrahedron》 |2001年第23期|共7页
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A.Fernandez-Mateos; M.Rentzsch; L.Rodriguez Sanchez; R.Rubio Gonzalez;
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1. Nucleophilic displacement of homoallylic tosylates: influence of steric hindrance and conformational rigidity [J] . A.Fernandez-Mateos, M.Rentzsch, L.Rodriguez Sanchez, Tetrahedron . 2001,第23期

机译：均烯丙基甲苯磺酸盐的亲核取代：位阻和构象刚度的影响
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8. Can the Rigidity of a Side Chain Liquid Crystalline Polymer Backbone Influence the Mechanism of Distortion of Its Random-Coil Conformation [R] . Percec, V., Tomazos, D. 1988

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Nucleophilic displacement of homoallylic tosylates: influence of steric hindrance and conformational rigidity

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