Diastereoselective preparation of (S)-(1,4,4-trimethylpyrrolidin-3-yl) amine, a new chiral 1,2-diamine for thiourea-type organocatalysts

Camps P.; Galdeano C.; Mu?oz-Torrero D.; Rull J.; Calvet T.; Font-Bardia M.

首页> 外文期刊>Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry >Diastereoselective preparation of (S)-(1,4,4-trimethylpyrrolidin-3-yl) amine, a new chiral 1,2-diamine for thiourea-type organocatalysts

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Diastereoselective preparation of (S)-(1,4,4-trimethylpyrrolidin-3-yl) amine, a new chiral 1,2-diamine for thiourea-type organocatalysts

机译：非对映选择性制备（S）-（1,4,4-三甲基吡咯烷-3-基）胺，一种新的手性1,2-二胺，用于硫脲类有机催化剂

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The enantioselective synthesis of the title compound, its conversion into a thiourea-type organocatalyst and the behavior of this organocatalyst in several enantioselective Michael reactions are described.

机译：描述了标题化合物的对映选择性合成，其转化为硫脲型有机催化剂以及该有机催化剂在几种对映选择性迈克尔反应中的行为。

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《Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry》 |2011年第7期|共7页
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Camps P.; Galdeano C.; Mu?oz-Torrero D.; Rull J.; Calvet T.; Font-Bardia M.;
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正文语种 eng
中图分类有机化学;
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1. Diastereoselective preparation of (S)-(1,4,4-trimethylpyrrolidin-3-yl) amine, a new chiral 1,2-diamine for thiourea-type organocatalysts [J] . Camps P., Galdeano C., Mu?oz-Torrero D., Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2011,第7期

机译：非对映选择性制备（S）-（1,4,4-三甲基吡咯烷-3-基）胺，一种新的手性1,2-二胺，用于硫脲类有机催化剂
2. Enhancement of the diastereoselectivity in the addition of trimethylsilyl cyanide to chiral aldimines by catalysis with a chiral 1,2-diamine: unexpected mechanistic results [J] . Leclerc E., Henryon V., Mangeney P. Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2000,第17期

机译：通过手性1,2-二胺催化，在向手性醛亚胺中添加三甲基甲硅烷基氰化物的非对映选择性增强：意想不到的机理结果
3. Bifunctional primary amine 2-aminobenzimidazole organocatalyst anchored to trans-cyclohexane-1,2-diamine in enantioselective conjugate additions of aldehydes [J] . Fernandes Talita de A., Vizcaino-Milla Pascuala, Ravasco Joao M. J. M., Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2016,第2a3期

机译：在醛的对映选择性共轭加成中，将双功能伯胺2-氨基苯并咪唑有机催化剂固定在反式环己烷-1,2-二胺上
4. Diastereoselective nitroaldol reaction catalyzed by chiral copper-diamine complexes. [C] . Rafal Kowalczyk, Jacek Skarzewski European Symposium on Organic Chemistry . 2009

机译：双滴度反应的硝基甲醇反应由手性铜二胺配合物催化。
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机译：A部分：通过N-二苯基膦亚胺的还原/烷基化或去质子化/烷基化的非对映选择性合成保护的仲胺。 B部分：通过将有机金属试剂1,2-加成到N-二苯基膦亚胺和随后的烷基化反应来合成仲胺
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机译：1,2-二溴乙烷，中1,2-二氘代-1,2-二溴乙烷和手性1,2-二氘代-1,2-二溴乙烷的实验和从头算振动光谱

Diastereoselective preparation of (S)-(1,4,4-trimethylpyrrolidin-3-yl) amine, a new chiral 1,2-diamine for thiourea-type organocatalysts

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