Approaches to highly polar polymers with low glass transition temperatures. 1. Fluorinated polymers via a combination of ring-opening metathesis polymerisation and hydrogenation

摘要

The synthesis and hydrogenation of two fluorinated polymers is described. The products were characterised through a detailed study of their ~1H-, ~(13)C- and ~(19)F-NMR spectra, together with thermal and GPC analysis. Hydrogenation resulted in a significant lowering of the glass transition temperatures of the polymers.