Determination of kinetic and thermodynamic parameters of L-cysteine adsorption onto gold by the qcm technique

摘要

This article discusses the adsorption kinetics of a L-cysteine monolayer onto a gold surface by means of information obtained through the QCM technique. The results indicate that the adsorption process is rapid and follows the Langmuir isotherm, in which adsorption and desorption are considered. From these measurements the following parameter values were obtained: kd = (4.2 ± 0.4) x 10-3 s-1, ka = 75 ± 6 M-1 s-1, Keq=(1.8 ± 0.3) x 104 M-1 and ΔGads = - (5.8 ± 0.2) kcal mol-1.