Supramolecular Bisporphyrin Cages: Design and Ways of Self-Assembly of Supramolecular Bisporphyrin Structures for Molecular Nanomotors and Nanosensors

摘要

Self-assembly of supramolecular ensembles of coordination bisporphyrins was studied in reactions of meso-tettakis(3-hydroxyphenyl)porphyrinatozinc with LaCl_3, MnCl_2, CrCl_3, and SnCl_2 and exodentate ligands (l,4-diazabicyclo[2.2.2]octane and 4,4'-bipyridyl). A design and ways of self-assembly of bisporphyrins structures were developed.