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Improvement in the pitting resistance of Inconel-600 by nitrogen ions implantation

机译:氮离子注入提高Inconel-600的耐点蚀性

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摘要

The surface of Ni-Cr-Fe (Inconel-600) alloy was modified by implanting 500 keV nitrogen ions at room temperature using pelletron accelerator to dose of 1.87 x 10(14) ions/cm(2). X-ray diffraction analysis of the ions implanted samples indicated the formation of Cr2N phase. Electrochemical testing of Inconel-600 alloy before and after the ions implantation was conducted using potentiodynamic tafel scan, potentiodynamic anodic polarization and electrochemical impedance spectroscopy techniques in an acidic saline solution. The higher anodic polarization slope (beta(a)), low cathodic polarization slope (beta(c)) and decrease in corrosion current density after ions implantation were attributed to the modification of passive film by the nitrogen ions. The scanning electron microscopy and electrochemical analyses of the ions implanted samples revealed an improvement in the pitting resistance of the alloy.
机译:Ni-Cr-Fe(Inconel-600)合金的表面通过在室温下使用压控加速器注入500 keV氮离子至1.87 x 10(14)离子/ cm(2)的剂量进行改性。离子注入样品的X射线衍射分析表明Cr2N相的形成。 Inconel-600合金在离子注入之前和之后的电化学测试是在酸性盐水溶液中使用电位动力学塔菲尔扫描,电位动力学阳极极化和电化学阻抗谱技术进行的。离子注入后,较高的阳极极化斜率(beta(a)),较低的阴极极化斜率(beta(c))和腐蚀电流密度的降低归因于氮离子对钝化膜的改性。离子注入样品的扫描电子显微镜和电化学分析表明,合金的抗点蚀性得到了改善。

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