Recent Trends in Experimental and Theoretical Investigations of Chemisorptions on Metal-Electrolyte Interface--I. In Situ Spectroscopic Studies and the Density Functional Theory Calculations

摘要

New trends in experimental and theoretical investigations of chemisorption on electrodes are considered on examples of in situ spectroscopic studies and the density functional theory calculations. The partial charge transfer during ionic and molecular adsorption from aqueous solutions on coinage and platinum metals and the thermodynamic uncertainty regarding the direction of the charge transfer are discussed.