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Ambient cure high solids acrylic resins for automotive refinish clear coat applications

机译:用于汽车修补漆清漆应用的环境固化高固含量丙烯酸树脂

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摘要

There is nowadays an increasing demand for low VOC systems in automotive refinish industry. These systems should also cure sufficiently fast as ambient temperature in order to reduce the investment in drying equipment and the time of repair. However, matching the stringent chemical and mechanical requirements associated with modium solid systems, and reaching a VOC level <420 g/l (from UK and Dutch legislation) is a challenge, especially if the coatings are cured at room temperature. Extensive research has been carried out on high solis resins making use of CARDURA~1 E10 (the glycidyl ester of VERSATIC acid) in conjunction with acrylic and methacrylic monomers. The efficient use of these building blocks allowed the cost-efective production of resins matching all coating requirements at a VOC level below 420 g/l after cure at ambient as wel as elevated temperatures. This ambient cure clear coat systems exhibit a very good overall performance and should therefore form a good starting point for very high solids ccrylic-urethane coatings for automotive refinish applications.
机译:如今,汽车修补漆行业对低VOC系统的需求不断增长。这些系统还应在环境温度下足够快地固化,以减少对干燥设备的投资和维修时间。但是,要满足与中等固体系统相关的严格化学和机械要求,并达到VOC含量<420 g / l(来自英国和荷兰的法规),这是一个挑战,特别是如果涂料在室温下固化的话。利用CARDURA〜1 E10(VERSATIC酸的缩水甘油酯)与丙烯酸和甲基丙烯酸单体结合使用,对高丙烯酸树脂进行了广泛的研究。这些构件的有效使用使树脂能够在环境温度(如高温)下固化后,以低于420 g / l的VOC水平,经济地生产符合所有涂料要求的树脂。这种环境固化的透明涂料体系表现出非常好的整体性能,因此应该为汽车修补漆应用中非常高固含量的丙烯酸聚氨酯涂料提供一个良好的起点。

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