Quinoxaline derivatives as long wavelength photosensitizers in photoinitiated cationic polymerization of diaryliodonium salts

摘要

The present paper is focused on visible light initiated cationic polymerizations. Photoinitiated polymerization of representative vinyl ether and oxirane monomers using two quinoxaline derivatives; namely (2-(2,3-dihydrobenzo [b][1,4]dioxin-6-yl)-3-(2,3-dihydrobenzo[b]-[1,4]dioxin-7-yl)-5-(2,3- dihydrothieno[3,4-b][1,4]dioxin-5-yl)-8-(2,3-dihydrothieno[3,4-b][1,4] dioxin-7yl) quinoxaline) (DBQEd) and 2,3,5,8-tetra(thiophen-2-yl)quinoxaline (TTQ) are studied. Novel dyes based on the quinoxaline skeleton are employed as efficient photosensitizers in cationic photopolymerizations. Polymerizations were initiated at room temperature upon irradiation with long-wavelength UV and visible lights in the presence of diphenyliodonium hexafluorophosphate (Ph _2I ~+PF _6 ~-). The progress of the polymerizations was monitored by optical pyrometry (OP). Solar irradiation is also employed to carry out the cationic polymerization of a diepoxide monomer in the presence of air.