Mathematical modelling of precious metals catalytic converters for diesel NO{sub}x reduction

摘要

Precious metal catalysts for NO{sub}x reduction in lean diesel engine exhaust conditions are characterized by a narrow temperature range of efficient operation and require high availability of reducing species in significant concentration.Consequently, there exists a large optimization potential in the design and control of lean-NO{sub}x catalytic conversion systems. A mathematical model of the transport and chemical phenomena in platinum-based lean-NO{sub}x catalysts was formulated, based on the experience with analogous models for gasoline three-way catalysts. A simplified four-reaction scheme is employed, considering the oxidation of CO, H{sub}2 and hydrocarbons (HCs), as well as the reaction between NO{sub}x and HCs. Results arecompared with previously published laboratory and engine data in order to assess the capacity of this approach in representing real-world behaviour of Pt-based lean-NO{sub}x catalysts. Initial results illustrate the power and flexibility of the model,which is able to predict the NO{sub}x conversion characteristics in model gas tests as well as in full-scale engine tests with reasonable accuracy