PREPARATION, ELECTRICAL PROPERTIES, AND SELF-ORGANIZATION OF ELECTRICALLY CONDUCTIVE LANGMLTR-BLODGETT FILMS CONTAINING REGIOCONTROLLED HEAD-TO^TAIL POLY(3-HEXYLTHIOPHENE)

摘要

Langmuir-Blodgett CLB technique and self assembly method have been frequently used to create the nanostrucaire and molecular organization of functional polymers. Through the use of our mixed LB system, it is possible to fabricate ultra thin films with the nano-scale. and superlatdce structures from a wide variety of conductive polymers. The: final , nanostructure. and molecular organization and hence their electrical arid optical properties ultimately depend on the structure of the molecule being manipulated and the nature of their imermolecular interactions. An effective design strategy must be aimed at using the-molecular self-organization properties with the LB manipulation because both the well-defined layer- structure and molecular organization are given by these molecular engineering.