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Dynamics of Electrospinning of Poly(caprolactone) via a Multi-Nozzle Spinneret Connected to a Twin Screw Extruder and Properties of Electrospun Fibers

机译:经由双喷嘴挤出机的多喷嘴喷丝头电纺聚己内酯的动力学及电纺纤维的性能

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摘要

Conventional electrospinning is a simple process, suitable for the processing of solvated polymers at relatively low rates. It lacks the capabilities of conveying of solids, mixing of polymeric resins and devolatilization and has limited capabilities in melting and incorporation of fillers, including nanoparticles. The use of a twin screw extruder as the front end of the electrospinning process provides these capabilities but only becomes feasible at relatively high throughput rates. Such high rates of electrospinning can only be achieved by using multi-nozzle spinnerets. However, the dynamics of electrospinning processes using multi-nozzle spinnerets has not been well studied. Here a multi-nozzle spinneret attached to a hybrid twin screw extrusion and electrospinning apparatus was employed for the characterization of the dynamics in terms of the electrospun mesh thickness distributions of poly(caprolactone), PCL, as a function of the principal parameters of the electrospinning process, i.e., applied voltage, distance of separation between the spinneret die, and the collector, i.e., a conductive mandrel, and its rotational speed. PCL fiber diameter and orientation distributions, as well as the thickness, crystallinity, and mechanical properties of the non-woven meshes, were characterized to gain a basic understanding of how the electrospun mesh properties develop as a function of process parameters in the multi-nozzle configuration.
机译:常规的静电纺丝是一种简单的方法,适用于以相对较低的速率加工溶剂化的聚合物。它缺乏固体的输送,聚合树脂的混合和脱挥发分的能力,并且在熔化和掺入包括纳米颗粒在内的填料方面能力有限。使用双螺杆挤出机作为静电纺丝工艺的前端可提供这些功能,但仅在相对较高的生产率下才可行。如此高的静电纺丝速率只能通过使用多喷嘴喷丝头来实现。但是,尚未对使用多喷嘴喷丝头的静电纺丝过程的动力学进行很好的研究。在这里,使用连接到混合双螺杆挤出和电纺丝设备上的多喷嘴喷丝板,根据电纺丝的主要参数,根据聚己内酯,PCL的电纺网孔厚度分布来表征动力学。处理,即施加的电压,喷丝头模具与集电器之间的分离距离(即导电芯轴)及其转速。对PCL纤维的直径和方向分布以及厚度,结晶度和非织造网眼的机械性能进行了表征,以基本了解电纺网眼性能如何随多喷嘴工艺参数的变化而发展。组态。

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