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Titanium carbide precipitation in Ti-22Nb alloy fabricated by metal injection moulding

机译:金属注射成型Ti-22Nb合金中碳化钛的析出

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Metal injection moulding was applied to fabricate Ti-22Nb alloy as a low modulus material for biomedical applications. Tensile test specimens were injection moulded, followed by debinding and sintering. Sintering was at 1500℃ for 4 h under vacuum (10~(-3) Pa). Selected as-sintered Ti-22Nb samples were hot isostatically pressed at 915℃/ 100 MPa for 2 h. The nature of the titanium carbide precipitates in the as-sintered Ti-22Nb alloy was investigated. Selected area electron diffraction patterns revealed that the carbides are Ti_2C with a fcc structure. The calculation of the phase diagram showed a significant decrease of carbon solubility in Ti-22Nb compared with that in Ti from 500 to 1500 ℃, contributing to the carbide precipitation in Ti-22Nb. Due to the carbide precipitation, the as-hipped Ti-22Nb alloy exhibited higher tensile strength but lower elongation than conventionally processed Ti-22Nb.
机译:金属注射成型被应用于制造Ti-22Nb合金,作为低模量材料用于生物医学应用。拉伸测试样品注射成型,然后脱脂和烧结。在真空(10〜(-3)Pa)下于1500℃烧结4 h。将选定的烧结Ti-22Nb样品在915℃/ 100 MPa下进行等静压2 h。研究了刚烧结的Ti-22Nb合金中碳化钛沉淀物的性质。选定区域的电子衍射图表明,碳化物是具有fcc结构的Ti_2C。相图的计算表明,从500到1500℃,Ti-22Nb中的碳溶解度比Ti中的碳溶解度显着降低,这有助于Ti-22Nb中的碳化物沉淀。由于碳化物的沉淀,与常规加工的Ti-22Nb相比,刚堆积的Ti-22Nb合金具有更高的拉伸强度,但延伸率却更低。

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