Optical Properties of PMMA Doped With Erbium(III) and Ytterbium(III) Complexes

摘要

In this article, we report the fabrication and optical/ spectroscopic properties of polymethylmethacrylate (PMMA) doped with rare earth (RE) (Er~(3+) and Er~(3+)/ Yb~(3+)) ions. Infrared spectroscopy revealed only very weak O-H stretching vibration peaks in the samples, which is important if satisfactory photoluminescence is to be observed at 1530 nm. Measurement of transmission spectra in the wavelength ranges from 300 to 700 nm for Er~(3+)-doped samples and from 900 to 1050 nm for Yb~(3+) -doped samples enabled us to observe the ~4G_(11/2) (377 nm) and ~2H_(11/2) (519 nm) transmission bands typical for Er~(3+)-doped samples, as well as the ~2F_(5/2) (975 nm) band typical for Yb~(3+)-doped samples. Under excitation at 980 nm, at room temperature, the characteristic Er~(3+) emission at 1530 nm was also observed with improving trend when the higher RE concentrations were applied. The results indicate that the PMMA reveals very low tendency to the RE clustering, which together with low cost and easy fabrication make it a material with a great potential in the active photonics devices.