Layered Silicate Nanocomposites Based on Various High-Functionality Epoxy Resins.Part II:The Influence of an Organoclay on the Rheological Behavior of Epoxy Prepolymers

摘要

The effect of an organically surface modified layered silicate on the viscosity of various epoxy resins of different structures and different functionalities was investigated.Steady and dynamic shear viscosities of the epoxy resins containing -10 wt% of the organoclay were determined using parallel plate rheology.Viscosity results were compared with those achieved through addition of a commonly used micron sized CaCO_3 filler.It was found that changes in viscosities due to the different fillers were of the same order,since the layered silicate was only dispersed on a micron-sized scale in the monomer (prior to reaction),as indicated by X-ray diffraction measurements.Flow activation energies at a low frequency were determined and did not show any significant changes due to the addition of organoclay or CaCO_3.Comparison between dynamic and steady shear experiments showed good agreement for low layered silicate concentrations below 7.5 wt%,i.e. the Cox-Merz rule can be applied.Deviations from the Cox-Merz rule appeared at and above 10 wt% although such deviations were only slightly above experimental error.Most resin organoclay blends were well predicted by the Power Law model,only concentrations of 10 wt% and above requiring the Herschel-Buckley (yield stress) model to achieve better fits.Wide-angle X-ray measurements have shown that the epxoy resin swells the layered silicate with an increase in the interlayer distance of approximately 15 A,and that the rheology behavior is due to the lateral,micron-size of these swollen tactoids.