Dynamic Mechanical Study of Epoxy, Epoxy/Glass, and Glass/Epoxy/Wood Hybrid Composites Aged in Various Media

摘要

It was proposed and subsequently established that wrapping of red oak wood crossties with epoxy impregnated glass fiber composites will impart longer service life and better stiffness and strength characteristics to these hybrid ties than conventional ones and will help them better withstand environmental extremes. The objective was to understand the degrading effects of aqueous (distilled water), saline (NaCl), acidic (HCl), and alkaline (NaOH) solutions, as well as accelerated aging and freeze/thaw cycling environments on the dynamic and static mechanical properties of these hybrid materials (i.e., wood, wrapped with fiber reinforced resin) and their components. Also micrographs of composite samples, obtained through scanning electron microscopy (SEM), were studied to determine the failure mechanism of composite specimens aged in different environments. Results showed that immersion in aging media lowered the glass transition temperature (T_g) and enhanced apparent phase separation in the samples because of polymer plasticization. In water immersion, the T_g and the stiffness increased with time owing to continued resin curing. At ambient temperature, sustained load had little effect on the mechanical behavior of the aged samples. The extent of degradation was the least for samples aged in salt solution. Soaking in room-temperature acid solution was most damaging to pure red oak wood samples. Six-cycle aging did not damage the neat resin or the hybrid samples, whereas it damaged pure wood specimens. Therefore, the composite wrapping around the wood core of the hybrid sample protected it sufficiently, thereby preventing damage to the hybrid specimen during the aging process.