Study of the Modification of the Properties of (PP/EPR) Blends With a View to Preserving Natural Resources When Elaborating New Formulation and Recycling Polymers

摘要

The aim of the present work is to study how CaCO3, very abundant on earth, can be blended with polypropyl-ene/ethylene propylene rubber (PP/EPR) either to preserve natural resources when elaborating virgin formulations or to simulate mixtures of waste made of CaCO3 filled PP with PP/EPR which could result from end-of-life-vehicles (ELV). The article focuses on the studies of PP/EPR blends, used in the manufacture of automobile fenders, in the presence of nano-CaCO3 and compatibil-izers. Blends of various compositions (with and without compatibilizer and nanoparticles) were prepared using a corotating twin-screw extruder. The results were compared with the ones presented by a commercial (PP/ EPR) blend. The experiments included mechanical tests, differential scanning calorimetry, scanning electron microscopy, and dynamic mechanical analysis experiments. The presence of the compatibilizers in the (PP/ EPR) blends decreases the size of elastomer particles, improves the adherence to the interface and improves the mechanical properties. The nano-CaCO3 would also seem to act as a nucleating agent in the PP/EPR matrix; it increases the cristallinity and the Young modulus of the blends.