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Formulation of New Synthetic Binders: Thermomechanical Properties of Resin/Recycled Polymer Blends

机译:新型合成粘合剂的配方:树脂/再生聚合物共混物的热机械性能

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摘要

Synthetic binders are special paving materials manufactured by mixing polymers, resins, and oils. These materials may have improved mechanical properties as compared with the traditional modified bitumen. This work is part of a comprehensive study on the design of synthetic binders with selected mechanical properties. In this sense, upgraded mechanical properties of the final synthetic binder can be attained by understanding and correlating the mechanical properties of its individual constituents as a function of composition and temperature. With this aim, this work deals with the thermomechanical properties of recycled polymer/resin blends, over a wide range of temperature and composition. Recycled polymer/resin blends are thermorheo-logically complex materials, due to the development of multiphase domains depending on polymer concentration. Thus, these blends show a predominantly gel-like behavior at high polymer concentrations and a predominantly viscous behavior, with high thermal susceptibility, for low polymer concentrations. The dynamic viscosities of the blends, as a function of polymer concentration and temperature, can be predicted using a logarithmic mixing rule.
机译:合成粘合剂是通过混合聚合物,树脂和油类而制成的特殊铺路材料。与传统的改性沥青相比,这些材料可具有改善的机械性能。这项工作是对具有选定机械性能的合成粘合剂设计进行全面研究的一部分。从这个意义上说,最终合成粘合剂的机械性能可以通过理解和关联其各个成分的机械性能作为组成和温度的函数来获得。出于这个目的,这项工作涉及在广泛的温度和组成范围内回收的聚合物/树脂共混物的热机械性能。回收的聚合物/树脂共混物是热流变学上复杂的材料,这归因于取决于聚合物浓度的多相区域的发展。因此,这些共混物在高聚合物浓度下显示主要为凝胶状的行为,而在低聚合物浓度下显示主要为粘性的行为和高热敏感性。可以使用对数混合规则来预测共混物的动态粘度随聚合物浓度和温度的变化。

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