Synthesis and characterization of two new niobium(V) diperoxo complexes containing 8-quinolinolate as the ligand

vinicius de Oliveira; Rosane Aguiar da Silva San Gil; Elizabeth Roditi Lachter

首页> 外文期刊>Polyhedron: The International Journal for Inorganic and Organometallic Chemistry >Synthesis and characterization of two new niobium(V) diperoxo complexes containing 8-quinolinolate as the ligand

【24h】

Synthesis and characterization of two new niobium(V) diperoxo complexes containing 8-quinolinolate as the ligand

机译：两种以8-喹啉酸酯为配体的新型铌（V）双二氧杂配合物的合成与表征

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Two new diperoxo complexes of niobium using 8-quinolinolate (Q) as the ligand, K[NbOH(O_2)_2Q](centre dot)2H_2O (1) and K[Nb(O_2)_2Q_2](centre dot)3H_2O (2), have been synthesised and characterised structurally by elemental analysis, IR and NMR (~1H, ~(13)C, ~(93)Nb) spectroscopy. The ~1H, ~(13)C NMR signals of the free ligand undergo shift on complexation.

机译：使用8-喹啉酸酯（Q）作为配体的两个新的铌双二氧杂配合物K [NbOH（O_2）_2Q]（中心点）2H_2O（1）和K [Nb（O_2）_2Q_2]（中心点）3H_2O（2）通过元素分析，IR和NMR（〜1H，〜（13）C，〜（93）Nb）光谱进行合成和结构表征。游离配体的〜1H，〜（13）C NMR信号在络合时发生位移。

著录项

来源
《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2001年第20期|共3页
作者
vinicius de Oliveira; Rosane Aguiar da Silva San Gil; Elizabeth Roditi Lachter;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;无机化学;
关键词
niobium peroxo complexes; ~(93)nb nmr; 8-quinolinol; diperoxo complexes; niobium; heteroligands;

机译：铌过氧配合物;〜（93）nb nmr;8-喹啉;二过氧配合物;铌;杂配体;

相似文献

外文文献
中文文献
专利

1. Synthesis and characterization of two new niobium(V) diperoxo complexes containing 8-quinolinolate as the ligand [J] . vinicius de Oliveira, Rosane Aguiar da Silva San Gil, Elizabeth Roditi Lachter Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2001,第20期

机译：两种以8-喹啉酸酯为配体的新型铌（V）双二氧杂配合物的合成与表征
2. Synthesis and Characterization of Niobium and Tantalum Complexes with Bidentate Ligand and its use in Ring Opening Polymerization of e-Caprolactone [J] . Yahya F. Al-Khafaji, Mohammed R. Al-Lami, Ahmed S. Abbas Asian Journal of Chemistry: An International Quarterly Research Journal of Chemistry . 2018,第2期

机译：铌和钽配合物与二齿配体的合成与表征及其在E-己内酯的开环聚合中的应用
3. New alkylimido niobium complexes supported by guanidinate ligands: Synthesis, characterization, and migratory insertion reactions [J] . Elorriaga D., Carrillo-Hermosilla F., Anti?olo A., Organometallics . 2012,第5期

机译：胍盐配体支持的新型烷基亚氨基铌配合物：合成，表征和迁移插入反应
4. Synthesis and Characterization of Mono and Mixed Ligand, Ni(II), Pd(II) and Pt(II) Complexes of S-5-Phenyl -1, 3, 4-Oxadiazole-2-yl Benzothioate with some Tertiary Diphosphines Ligands [C] . R. A. Saleh, H. A. Mohammad, T. I. Gerber, International Conference and Workshops on Basic and Applied Sciences . 2017

机译：S-5-苯基-1,3,4-二氧化氮-2-基苯并噻吩二叔二膦配体的S-5-苯基-1,3,4-二氮唑-2-基苯甲酸酯的单氧和混合配体，Ni（II），Pd（II）和Pt（II）配合物的合成及表征
5. Synthesis and Characterization of Rhodium(III) Complexes Containing a Bisphosphine Ligand and Variations of a Monodentate Ligand [D] . Medina, Joseph T. 2020

机译：含有二膦配体的铑（III）络合物的合成与表征，单张膦酸配体的变化
6. Synthesis of (Arylmido)niobium(V) Complexes ContainingKetimide Phenoxide Ligands and Some Reactions with Phenols and Alcohols [O] . Natta Srisupap, Kritdikul Wised, Ken Tsutsumi, 2018

机译：含（Arylmido）铌（V）配合物的合成酮亚胺苯酚配体以及与酚和醇的某些反应
7. Synthesis and Characterization of Niobium and Tantalum Complexes with Bidentate Ligand and its use in Ring Opening Polymerization of e-Caprolactone [O] . Yahya F. Al-Khafaji, Mohammed R. Al-Lami, Ahmed S. Abbas, 2018

机译：铌和钽配合物与二齿配体的合成与表征及其在E-己内酯的开环聚合中的应用
8. Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 90. (1) Synthesis of the Complexes (W2M2(mu-CO)(mu-CMe)(mu3-CMe)-(Mu-PPh2)2(CO)3(eta-C5H5)2) (M = Rh or Ir) and Related Tetra- and Penta-nuclear Metal Compounds: Interconversion of Ketenyl and Lambda(5) -Phospha-alkyne Ligands Bridging Tungsten-Rhodium Bonds. [R] . Davies, S. J., Stone, F. G. 1989

机译：具有桥接卡宾或卡宾配体的多核金属配合物的化学。部分90.（1）配合物的合成（W2m2（mu-CO）（mu-Cme）（mu3-Cme） - （mu-pph2）2（CO）3（eta-C5H5）2）（m = Rh或Ir）和相关的四核和五核金属化合物：Ketenyl和Lambda（5）-phospha-alkyne配体桥联钨 - 铑键的相互转化。

Synthesis and characterization of two new niobium(V) diperoxo complexes containing 8-quinolinolate as the ligand

摘要

著录项

相似文献

相关主题

期刊订阅