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Nature of the Blue-Phase-III-isotropic critical point: An analogy with the liquid-gas transition

机译:蓝相III各向同性临界点的性质:与液-气过渡类似

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摘要

The analogy with the liquid-gas critical point is analyzed to clarify the nature of the pretransitional behavior of physical properties in the vicinity of the Blue-Phase-m-isotropic transition in chiral liquid crystalline systems. The analogy is unusual: temperature serves as the ordering field and entropy plays the role of the order parameter. Both mean field and parametric equations of state are formulated in terms of scaling fields. The scaling fields are linear combinations of the physical fields, which are temperature and chirality. It is shown that mixing of the physical field variables naturally leads to a strong asymmetry with respect to the transition temperature in the behavior of the physical properties that cannot be described by simple power laws. While the mean field theory gives a good description of the experimental data, the scaling theory, if one incorporates mixing of the field variables, gives even better agreement with the experimental data, placing this transition in the same universality class as the three-dimensional Ising model. [References: 39]
机译:分析了与液体-气体临界点的类比,以阐明手性液晶系统中蓝相-m-各向同性转变附近物理性质的过渡前行为的性质。这个比喻是不寻常的:温度是有序字段,而熵起着有序参数的作用。平均场和参数状态方程都是根据比例场制定的。标度场是物理场的线性组合,即温度和手性。结果表明,物理场变量的混合自然会导致物理性能的转变温度相对于转变温度具有很大的不对称性,而这是无法用简单幂定律描述的。虽然平均场理论可以很好地描述实验数据,但是比例缩放理论(如果结合了场变量的混合)则可以更好地与实验数据相吻合,从而使这种转变与三维Ising具有相同的通用性。模型。 [参考:39]

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