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Brownian motion of interacting nonspherical tracer particles: General theory

机译:相互作用的非球形示踪剂粒子的布朗运动:一般理论

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摘要

A general theoretical framework is developed to describe the tracer-diffusion properties of nonspherical Brownian tracer particles that interact with the other particles in a multicomponent colloidal suspension of generally nonspherical particles, in the absence of hydrodynamic interactions. Here we present the derivation of the generalized Langevin equation (GLE) for the linear and angular velocity describing the Brownian motion of the tracer particle. In addition to the dissipative plus the random force and torque exerted by the solvent, this GLE contains the dissipative plus random force and torque due to the direct interactions with the other particles. An exact and general expression is derived for the time-dependent friction tensor that embodies the effects of the latter. Using a generalized Wertheim-Lovett's relation, this expression is cast in two alternative but equivalent forms. The long-time and short-time limits (in reference to the structural relaxation time tau(I)) are also discussed.
机译:建立了一个通用的理论框架来描述非球形布朗示踪粒子的示踪扩散特性,该非球形布朗示踪粒子在没有流体动力学相互作用的情况下,与一般非球形粒子的多组分胶体悬浮液中的其他粒子相互作用。在这里,我们介绍了线性和角速度的广义Langevin方程(GLE)的推导,该线性和角速度描述了示踪粒子的布朗运动。除了耗散性加上溶剂施加的随机作用力和扭矩外,由于与其他粒子的直接相互作用,该GLE还包含耗散性加上随机作用力和扭矩。对于随时间变化的摩擦张量,可以得出一个精确而通用的表达式,体现了后者的作用。使用广义的Wertheim-Lovett关系,此表达式以两种替代但等效的形式进行转换。还讨论了长期和短期极限(参考结构弛豫时间tau(I))。

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