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Critical broadening of the vibrational linewidth by concentration fluctuations

机译:浓度波动对振动线宽的临界加宽

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摘要

We report high pressure measurements of the half-width and shift of the vibrational Raman spectrum of nitrogen in the homogeneous helium-nitrogen fluid binary mixture. The measurements have been performed using a diamond anvil cell in a large range of pressure p, temperature T, and composition x including the critical region. In approaching the critical line a considerable broadening has been observed which is shown to be due to critical concentration fluctuations. This proves that the order parameter distribution can explicitly be determined by a general experimental method.
机译:我们报告了在均匀的氦-氮流体二元混合物中氮气的振动半边宽和位移的高压测量结果。使用金刚石砧盒在很大的压力p,温度T和包括临界区域的成分x范围内进行了测量。在接近临界线时,观察到相当大的展宽,这是由于临界浓度波动引起的。这证明了可以通过常规的实验方法来明确确定阶次参数分布。

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