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Strong-field-approximation theory of high-order harmonic generation by polyatomic molecules

机译:多原子分子产生高次谐波的强场近似理论

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A theory of high-order harmonic generation by arbitrary polyatomic molecules is introduced. A polyatomic molecule is modeled by an (N + 1)-particle system, which consists of N heavy atomic (ionic) centers and an electron. After the separation of the center-of-mass coordinate, the dynamics of this system is reduced to the relative electronic and nuclear coordinates. Various versions (with or without the dressing of the initial and/or final molecular state) of the molecular strong-field approximation are introduced. For neutral polyatomic molecules the derived expression for the T-matrix element takes a simple form. The interference minima in the harmonic spectrum are explained as a multiple-slit type of interference. This is illustrated by numerical examples for the ozone (O-3) and carbon dioxide (CO2) molecules.
机译:介绍了由任意多原子分子产生高次谐波的理论。多原子分子由(N +1)粒子系统建模,该系统由N个重原子(离子)中心和电子组成。在质心坐标分离之后,该系统的动力学被减小为相对的电子坐标和核坐标。介绍了分子强场近似的各种形式(具有或不具有初始和/或最终分子状态的修整)。对于中性多原子分子,T矩阵元素的派生表达采用简单形式。谐波频谱中的最小干扰被解释为多缝类型的干扰。臭氧(O-3)和二氧化碳(CO2)分子的数值示例对此进行了说明。

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