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Blectrochemical determination of dissolved Uranium in krka river estuary

机译:电化学法测定克尔卡河河口溶解态铀

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摘要

The applicability of the previously developed method for electrochemical determination of dissolved uranium concentration has been tested on natural water samples taken from the Krka river estuary during various seasons and along different depth profiles. The method is based on the following treatment of the sample: destroying the uranyl-carbonato complexes by adjusting the pH to 3, enabling the formation of adsorbable uranyl-hydroxo complexes by adjusting the pH to 6.5-7.0 and measurement by cathodic stripping voltammetry technique.
机译:在从不同季节和不同深度剖面的克尔卡河河口抽取的天然水样上,已经测试了以前开发的用于电化学测定溶解铀浓度的方法的适用性。该方法基于样品的以下处理:通过将pH值调节到3来破坏铀酰-羰基配合物,通过将pH值调节到6.5-7.0能够形成可吸附的铀酰-羟基配合物,并通过阴极溶出伏安法进行测量。

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