Kinetics of substitution at [tris(3,5-dimethylpyrazolyl)-hydroborato]molybdenum nitrosyl dihalides by alcohols and by aniline

Saad Alshehri; John Burgess; Colin D. Hubbard; Christopher J. Jones; Amit K. Das

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Kinetics of substitution at [tris(3,5-dimethylpyrazolyl)-hydroborato]molybdenum nitrosyl dihalides by alcohols and by aniline

机译：[三（3,5-二甲基吡唑基）-氢硼酸]钼亚硝酰基二卤化物被醇和苯胺取代的动力学

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The kinetics of substitution by alcohols and by aniline at [tris(3,5-dimethylpyrazolyl)hydroborato]molybdenum nitrosyl dihalides in toluene solution at 298.2 K and at atmospheric pressure are reported and interpreted in terms of an associative mechanism.

机译：报道了在甲苯溶液中在298.2 K和大气压下[tris（3,5-二甲基吡唑基）氢硼酸酯]亚硝基二卤化钼上醇和苯胺的取代动力学，并根据缔合机理进行了解释。

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《Transition Metal Chemistry》 |2008年第4期|417-420|共4页
作者
Saad Alshehri; John Burgess; Colin D. Hubbard; Christopher J. Jones; Amit K. Das;
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作者单位

Chemistry Department University of Leicester Leicester LE1 7RH UK;

Chemistry Department University of Leicester Leicester LE1 7RH UK;

Chemistry Department University of Leicester Leicester LE1 7RH UK;

School of Chemistry University of Birmingham Edgbaston Birmingham B15 2TT UK;

School of Chemistry University of Birmingham Edgbaston Birmingham B15 2TT UK;

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1. Kinetics of substitution at [tris(3,5-dimethylpyrazolyl)-hydroborato]molybdenum nitrosyl dihalides by alcohols and by aniline [J] . Saad Alshehri, John Burgess, Colin D.Hubbard Transition Metal Chemistry . 2008,第4期

机译：[三（3,5-二甲基吡唑基）-氢硼酸]钼亚硝酰基二卤化物被醇和苯胺取代的动力学
2. Redox activity of bimetallic complexes based on tris(3,5-dimethylpyrazolyl)borato molybdenum(II) and tungsten(II) nitrosyls. Complexes derived from ethane-1,2-diol and the crystal structure of anti-[Mo(NO){HB(3,5-Me2C3HN2)3}(OCH2CH2O)]2 · 4CHCl3 [J] . Piotr P. Romańczyk, Matylda N. Guzik, Andrzej J. Wlodarczyk Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2007,第6期

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Kinetics of substitution at [tris(3,5-dimethylpyrazolyl)-hydroborato]molybdenum nitrosyl dihalides by alcohols and by aniline

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