Experimental and theoretical studies on noble metal decorated tin oxide flower-like nanorods with high ethanol sensing performance

摘要

This study reports a facile solvothermal method for the synthesis of tin oxide (SnO_2) flower-like nanorods with dominant (110) crystal surface, which could be further decorated with varying amounts of noble metals, (gold (Au) and palladium (Pd)) to enhance the gas-sensing properties. Analysis of the gas-sensing results reveal that the decoration of Au and Pd nanoparticles on the surface of the SnO_2 nanorods is advantageous in: (ⅰ)enhancing the sensitivity towards ethanol (9-15 times); (ⅱ) reducing the response/recovery time (by 15-40s), and (ⅲ) significantly decreasing the optimum operating temperature (from 250 to 175 ℃). Beyond physical experiments, molecular dynamics (MD) method was also conducted to quantify diffusivity, adsorption and reaction capabilities of ethanol on SnO_2(110) plane and to better understand the role of noble metals in enhancing the gas-sensing performance of Sno_2. The findings in this study will be useful for future design of metal oxide nanocomposites with specific crystal surface for achieving high performance in surface-governed applications.