Facile Synthesis of Polypyrrole Nanofibers/Co-MOF Composite and Its Lithium Storage Properties

摘要

Metal-organic frameworks (MOFs) have recently emerged as promising electrode materials for lithium-ion batteries (LIBs). However, poor electrical conductivity in most MOFs limits their electrochemical performance. In this work, the integration of flaky cobalt 1,4-benzenedicarboxylate (Co-BDC) MOF with conductive polypyrrole (PPy) nanofibers via in-situ growth strategy was explored for developing novel anode materials for LIBs. Electro-chemical studies showed that PPy/Co-BDC composites exhibited enhanced cycling performance (a reversible capacity of ca. 364 mA h g(-1) at a current density of 50 mA g(-1) after 100 cycles) and rate capability, compared with the pristine Co-BDC. The well dispersion of Co-BDC on polypyrrole nanofibers and the decrease in charge-transfer resistance of the composite electrodes accounted for the improvement of electrochemical properties.