Influence of gamma irradiation on the thermal stability of blends of PP with previously treated sisal fiber

摘要

In this work, the thermal degradation of PP blends with previously treated sisal fiber (10mm), and y irradiated in air at different doses (10, 25, 50, 60, 70 kGy), is studied. The treatment to which sisal fibers were previously submitted were : (a) the addition of a coupling agent (Silane A-172), 1/100 by weight, (b) a chemical treatment at different times (1/2 and 1 h) with NaOH, and (c) the addition of a functionalized polypropylene known as Polybond 3150 and 3200, 5/100 by weight. After the treatment, mixtures of PP with 20/100 of sisal fibers were prepared. Their thermograms were analyzed using different integral methods in order to evaluate the activation energy. For the blend of PP with sisal fibers, previously treated for l h with NaOH, the largest value amounted to 60 kJ/mol (approximately) for irradiation doses under 40 kGy. At higher irradiation doses a decay on the activation energy was observed. When the fibers were treated with NaOH for 30 min, the activation energy decreased from 55 kJ/mol to values under 45 kJ/mol, when subjected to high irradiation doses (> 50 kGy). This can be explained by the fact that, when sisal fibers are treated with NaOH solutions over a longer time, impurities and lignin are better removed resulting in a higher surface roughness, as a consequence a higher polymer to fiber interaction is possible, which, in turn, makes the blend more stable at low irradiation doses. Instead, when the sisal fibers were treated with silane, the activation energy for thermal degradation decreased at higher irradiation doses until an inversion of the tendency was observed for the 50 kGy dose; this may imply that this irradiation induces the production of PP-filler bridges. With composites containing compatibilizers, a similar behavior as with silane was observed but with the inversion on the tendency at 70 kGy. From these results, it can be concluded that a l-h treatment with NaOH produces a higher thermal stability than the others. Moreover, this treatment has the best profit/cost ratio, which makes it commercially profitable when compared with others. The mathematical analysis shows that the blend of PP with NaOH-treated sisal fiber at the two treatment times (1 h and 1/2 h), showed competing degradation and single decomposition processes for the irradiation intervals between 0-50 kGy and 5O-70 kGy, respectively. Regarding the blends of PP with silane-treated sisal fiber or Polybond addition showed bimolecular decomposition behavior for both irradiation intervals.