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Effect of solvent on the ultrasonic degradation of poly(vinyl acetate)

机译:溶剂对聚醋酸乙烯酯超声降解的影响

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The ultrasonic degradation of poly(vinyl acetate) was carried out in six different solvents and two mixtures of solvents. The evolution of molecular weight distribution (MWD) with time was determined with gel permeation chromatography. The observed MWDs were analyzed by continuous distribution kinetics. A stoichiometric kernel that accounts for preferential mid-point break- age of the polymer chains was used. The degradation rate coefficient of the polymer in each solvent was determined from the model. The variations of rate coefficients were correlated with vapor pressure of the solvent, the Flory-Huggins polymer solvent interac- tion parameter and the kinematic viscosity of the solution. A lower saturation vapor pressure resulted in higher degradation rates of
机译:聚醋酸乙烯酯的超声降解是在六种不同的溶剂和两种溶剂的混合物中进行的。用凝胶渗透色谱法测定分子量分布(MWD)随时间的变化。通过连续分布动力学分析观察到的MWD。使用了占聚合物链中点断裂优先的化学计量核。由模型确定聚合物在每种溶剂中的降解速率系数。速率系数的变化与溶剂的蒸气压,Flory-Huggins聚合物溶剂相互作用参数和溶液的运动粘度相关。较低的饱和蒸气压导致较高的降解速度

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