Thermal degradation and their kinetics of biodegradable poly(butylene succinate-co-butylene terephthate)s under nitrogen and air atmospheres

摘要

In this study, thermal degradation and their related kinetics have been investigated mainly by means of thermal gravimetrical analyzer (TGA) under the dynamic nitrogen and air atmospheres for the chemically prepared biodegradable aliphatic-aromatic copolyesters of poly(butylene succinate-co-butylene terephthalate) (PBST). To further shed new lights on the comonomer molar composition and experimental condition dependences of thermal degradation kinetics, the as-known Friedman model was at first applied to quantitatively evaluate the kinetic parameters in terms of activation energy (E), degradation reaction order (n) and the frequency factor (Z). The results clearly demonstrated that thermal stabilities of these PBST copolyesters were substantially enhanced with the incorporation of more rigid butylene terephthalate comonomer, and tended to be much better in nitrogen than in air. Furthermore, the Friedman, Freeman-Carroll and Chang models were concurrently employed to quantitatively evaluate the thermal degradation kinetic parameters of the PBST copolyesters in nitrogen at different heating rates of 1, 2 and 5 K/min. It was found that the thermal degradation kinetic parameters for the PBST copolyesters were strongly dependent on the heating rate and calculating models. In addition, life-time parameters of the biodegradable PBST copolyesters were first calculated to predict the maximum usable temperatures, and this would be useful for practical application of these new bio-based green plastics. (c) 2005 Elsevier Ltd. All rights reserved.