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Preliminary evaluation of the use of elevated pressure to accelerate thermo-oxidative aging in composites

机译:使用高压促进复合材料热氧化老化的初步评估

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A study was conducted to evaluate the use of elevated pressure to accelerate the rate of thermo-oxidative degradation in poly- meric composite materials. The motivation for this work was based on earlier studies by Tsotsis [1,2], Kerr and Haskins [3] and by Ciutacu, et al. [4] which demonstrated that higher pressures of air or oxygen tended to increase the rate of degradation of polymeric composites. Moreover, accelerated aging methods are needed to evaluate materials which are to be used under long-term exposure to elevated temperature in oxidative environments such as the High-Speed Civil Transport (HSCT). The methodology proposed herein augments elevated temperature aging with elevated pressure to accelerate the rate of thermo-oxidative degradation. Tem- peratures below those used by previous workers were employed in order to avoid anomalous non-linear effects which can occur near the glass-transition temperature of polymeric materials. In the present work, Hexcel AS4/3501 -6 [ ± 45°]_2s shear and [+ 45°/0°/ -45°/90°]_2s quasi-isotropic Hexcel IM7/8552 open hole compression specimens were aged at 121℃ (250°F) at pressures of 0.101, 0.345, 1.03, and 1.72 MPa (14.7, 50, 150, and 250 psi). Three pressure vessels were designed and built to contain the prescribed pressures. These vessels were placed inside an oven and used an air bleed to recycle the air inside the vessels. For the open hole testing, a test method was derived from Boeing BSS 7260 to reduce the material required for each specimen. Specimens were tested as-made and after 1000 h exposure to each of the p
机译:进行了一项研究,以评估使用高压来加速聚合物复合材料中热氧化降解的速率。这项工作的动机是基于Tsotsis [1,2],Kerr和Haskins [3]以及Ciutacu等人的早期研究。 [4]证明较高的空气或氧气压力倾向于增加聚合物复合材料的降解速率。而且,需要加速老化方法来评估在诸如高速民用运输(HSCT)等氧化环境中长期暴露于高温下所使用的材料。本文提出的方法通过升高的压力来增强高温老化,以加速热氧化降解的速率。为了避免在聚合物材料的玻璃化转变温度附近出现异常的非线性效应,请使用低于先前工作人员使用的温度。在当前工作中,Hexcel AS4 / 3501 -6 [±45°] _2s剪切力和[+ 45°/ 0°/ -45°/ 90°] _2s准各向同性Hexcel IM7 / 8552裸眼压缩标本在121岁时效℃(250°F),压力为0.101、0.345、1.03和1.72 MPa(14.7、50、150和250 psi)。设计并建造了三个压力容器以容纳规定的压力。将这些容器放置在烤箱中,并使用放气来回收容器内部的空气。对于裸眼测试,从波音BSS 7260衍生了一种测试方法,以减少每个样本所需的材料。标本按原样进行测试,并在暴露于每种

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