Synthesis of (C5H5)2Zr(O2C)CH3 and (C5H5)2Zr(O2C)CH2CH3 for olefin polymerization

Juan Fernández; Jessely Molina; Tamara Rajmankina; José Arévalo; álvaro Parada

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Synthesis of (C5H5)2Zr(O2C)CH3 and (C5H5)2Zr(O2C)CH2CH3 for olefin polymerization

机译：（C5 H5 ）2 Zr（O2 C）CH3 和（C5 H5 ）2 Zr（O2 C）CH2 CH3 用于烯烃聚合

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(C5H5)2Zr(O2C)CH3 and (C5H5)2Zr(O2C)CH2CH3 complexes were synthesized, characterized and activated with MAO for ethylene polymerization. The highest catalytic activity was achieved at Al/Zr molar ratio of 3000 for both systems. The effects of the size of the R group in the carboxylate ligands, the Al/Zr molar ratio and reaction temperature on the catalytic activity and polymer properties were studied and discussed.

机译：（C5 H5 ）2 Zr（O2 C）CH3 和（C5 H5 ）2 Zr合成（O2 C）CH2 CH3 配合物，表征并用MAO活化进行乙烯聚合。对于这两个系统，在Al / Zr摩尔比为3000时实现了最高的催化活性。研究和讨论了羧酸根配体中R基团的大小，Al / Zr摩尔比和反应温度对催化活性和聚合物性能的影响。

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《Polymer Bulletin》 |2007年第5期|629-636|共8页
作者
Juan Fernández; Jessely Molina; Tamara Rajmankina; José Arévalo; álvaro Parada;
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Laboratorio de Polímeros Departamento de Química Facultad de Ciencias Universidad del Zulia Maracaibo Venezuela;

Laboratorio de Polímeros Departamento de Química Facultad de Ciencias Universidad del Zulia Maracaibo Venezuela;

Laboratorio de Polímeros Departamento de Química Facultad de Ciencias Universidad del Zulia Maracaibo Venezuela;

Laboratorio de Polímeros Departamento de Química Facultad de Ciencias Universidad del Zulia Maracaibo Venezuela;

Laboratorio de Polímeros Departamento de Química Facultad de Ciencias Universidad del Zulia Maracaibo Venezuela;

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1. Synthesis of (C5H5)2Zr(O2C)CH3 and (C5H5)2Zr(O2C)CH2CH3 for olefin polymerization [J] . Juan Fernandez, Jessely Molina, Tamara Rajmankina Polymer bulletin . 2007,第5期

机译：烯烃聚合用（C5H5）2Zr（O2C）CH3和（C5H5）2Zr（O2C）CH2CH3的合成
2. New O- and N-bonded zirconocene complexes and their catalytic properties in ethylene polymerization. X-ray crystal structure of (C5H5)(2)Zr{2,6-OC6H3(CH3)(2)}(2), (C5H5)(2)Zr{2,4,6-OC6H2(CH3)(3)}(2) and (C5H5)(2)Zr(CH3){CH(NC6H5)(2)} [J] . Benetollo F., Crosara L., Milani F., Journal of Organometallic Chemistry . 1998,第2期

机译：新的O和N键合的锆茂配合物及其在乙烯聚合反应中的催化性能。（C5H5）（2）Zr {2,6-OC6H3（CH3）（2）}（2），（C5H5）（2）Zr {2,4,6-OC6H2（CH3）（3）的X射线晶体结构）}（2）和（C5H5）（2）Zr（CH3）{CH（NC6H5）（2）}
3. SYNTHESIS, CHARACTERIZATION, AND CARBONYLATION OF THE ASYMMETRIC MONO-RING-FUNCTIONALIZED ZIRCONOCENES, (ETA(5)-C5H5)(ETA(5)-C5H4)P(C6H5)(2))ZR(CH3)X (X=CH3, CL) [J] . Tikkanen W., Lam KB., Ruekert K., Organometallics . 1995,第3期

机译：（ETA（5）-C5H5）（ETA（5）-C5H4）P（C6H5）（2））ZR（CH3）X（X = CH3，）的不对称单环功能锆茂的合成，表征和羰基化CL）
4. THE SYNTHESIS AND STRUCTURE OF A NEW LAYERED ALUMINIUM PHOSPHATE AL3P4OI63- 3(CH3(CH2)3NH3)+ [C] . A. M. Chippindale, Q. Huo, R. H. Jones, International Zeolite Conference . 1995

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5. Progress Towards the Synthesis of a Novel 4-Carbon Linked ansa-Zirconcocene: [(CH2C(CH3)C(CH3)CH 2)(3-t-BuC5H3)2]ZrCl 2. [D] . Shamberg, Jonathan M. 2014

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7. Front Cover: Synthesis and Electrochemical Behavior of Ferrocenyl- Functionalized Metallocenes M(η5 - C5 H5 )2 (EFc)2 (M = Ti, Zr; E = O, S, Se) (Eur. J. Inorg. Chem. 27/2018) [O] . Peter Frenzel, Marcus Korb, Alexander Hildebrandt, 2018

机译：前盖：二茂铁 - 官能化茂金属M（η5 - C5 H5）2（EFC）2（M = Ti，Zr; E = O，S，Se）（J.inorg。化学。27 / 2018年）
8. Synthesis and Characterization of the Mixed-Metal Alkylidyne Clusters RCFeCo2(CO)9H (R = CH3, C2H5, C6H5). [R] . Epstein, R. A., Withers, H. W., Geoffroy, G. L. 1978

机译：混合金属烷基炔团簇RCFeCo2（CO）9H（R = CH3，C2H5，C6H5）的合成与表征。

Synthesis of (C5H5)2Zr(O2C)CH3 and (C5H5)2Zr(O2C)CH2CH3 for olefin polymerization

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