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首页> 外文期刊>Organic letters >Catechol-Based Phosphoramidites: A New Class of Chiral Ligands for Rhodium-Catalyzed Asymmetric Hydrogenations
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Catechol-Based Phosphoramidites: A New Class of Chiral Ligands for Rhodium-Catalyzed Asymmetric Hydrogenations

机译：邻苯二酚基亚磷酰胺：铑催化不对称氢化的新型手性配体

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摘要

The synthesis and application of a new class of catechol-based phosphoramidites is described. Ees up to 99% were obtained in the rhodium-catalyzed asymmetric hydrogenation of dehydroamino acids and enamides.
机译：描述了一种新型的基于邻苯二酚的亚磷酰胺的合成和应用。在铑催化的脱氢氨基酸和酰胺的不对称加氢反应中，得到高达99％的Ees。

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  • 来源
    《Organic letters》 |2004年第9期|p. 1433-1436|共4页
  • 作者

    Rob Hoen; Michel van den Berg; Heiko Bernsmann; Adriaan J. Minnaard; Johannes G. de Vries; Ben L. Feringa;

  • 作者单位

    Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands;

    Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands;

    Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands;

    Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands;

    Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands;

    Department of Organic and Molecular Inorganic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands;

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  • 正文语种 eng
  • 中图分类 有机化学;
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